Abstract
The effect of nanocrystallite size on crystal structure and magnetic properties of off-stoichiometric Ni1.8Mn1.2Sn Heusler alloy has been investigated. XRD (X-Ray Diffraction) and HRTEM (High-Resolution Transmission Electron Microscopy) analysis revealed the presence of both the full Heusler (Ni2MnSn) L21 and inverse Heusler (Mn2NiSn) XA crystal symmetries. Hence, the sample can be treated as a natural composite of both phases. However, the magnetic analysis reveals that the magnetization does not follow a linear relationship with the volume fraction of the individual phases. Rather, the antiferromagnetic coupling between the two phases may be responsible for lowering the net magnetization. On the other hand, magnetization value further decreases for ball-milled sample (nanocrystallite size). Critical magnetic behavior analysis reveals that the magnetic ordering in bulk sample follows mean field theory, and for nanocrystalline sample, the magnetic ordering is a short-range type.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
