Abstract
Transition metal pyrophosphate material forms a robust polyanionic cathode family for sodium-ion batteries. Here, binary Na2(Fe1-yMny)P2O7 (0 ≤ y ≤ 1) system has been recently investigated by different groups, as Na2FeP2O7 is reported as a low-cost cathode with promising electrochemical performance and thermal stability. While the isostructural Na2FeP2O7 and Na2MnP2O7 assume triclinic P1‾ (#2) framework, pyrophosphate system shows structural diversity/polymorphism. Considering this, we have investigated the binary Na2(Fe1-xZnx)P2O7 (0 ≤ x ≤ 1) pyrophosphate family with anisostructural end members Na2FeP2O7 (P1‾, #2) and Na2ZnP2O7 (P42/n, #86). The current study reports solution combustion as well as solid-state preparation of novel Na2(Fe1-xZnx)P2O7 (0 ≤ x ≤ 1) family of materials, their structural and electrochemical characterizations. The degree of solid-solution formation and effect of Zn on Fe-redox activity in Na2(Fe1-xZnx)P2O7 (x = 0, 0.25) cathodes has been examined using electrochemical titration techniques such as galvanostatic intermittent titration (GITT) and potentiostatic intermittent titration (PITT) mode.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
