Abstract

The effect of deposition conditions on the growth structure of amorphous thin films of lithio-borate solid electrolyte was investigated by means of infrared absorption and complex impedance spectroscopies. Thin films of vitreous solid electrolyte in the alkali-oxide/borate-oxide system were grown by vacuum quasi-flash evaporation. The complex impedance measurements of the thin solid films in the sandwich geometry show a high ionic conductivity. Incorporation of lithium salt dopant has been also studied. The structure was determined using infrared absorption spectra which are sensitive to deposition conditions and to the amount of lithium incorporated.

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