Abstract

Alloying Pt with Rh significantly enhances the high temperature stress rupture strength and maintains both oxidation and corrosion resistance at elevated temperatures. Such unique property combination renders Pt-Rh alloys mainstay in space technology, glass and chemical industries. However, the exponential increase in the price of Rh in the past few years stirs an industrial concern. As a result, some industries are beginning to search for alternative alloys that can offer similar properties. This study conducted first-principles calculations to generate structural and elasticity data on binary Pt-Rh alloys using both supercell and virtual crystal approximation (VCA) approaches, to serve as a benchmark for new alternative Pt-based alloys.

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