Abstract
Germanium-based materials exhibit promising properties for applications in electronics, sensing, and catalysis. Gold-germanium clusters are of particular interest due to their potential for enhanced stability and tailored electronic properties. This study investigates the structures, bonding, and electronic properties of Au2Ge9ˉ and Au2Ge10ˉ clusters using anion photoelectron spectroscopy and theoretical calculations. The clusters were generated using laser vaporization and studied using anion photoelectron spectroscopy. Theoretical calculations employed density functional theory and coupled-cluster methods. Au2Ge9ˉ and Au2Ge10ˉ clusters exhibit weak aurophilic interactions between the two gold atoms. The gold atoms mimic the electronic and structural properties of germanium atoms, acting as surrogates within the cluster framework. Understanding the role of gold in these germanium clusters provides insights for designing novel materials with tailored properties for applications in catalysis, electronics, and other fields.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.