Abstract

This paper explains the role of molybdenum on the structural analysis of the investigated rare earth ion Pr3+ doped, lead borate (75 PbO — [25 – (x+y)]B2O3—yMoO3—xPr2O3) glass matrix has been discussed using the relation between Tg and structural parameters like average cross-link density (), average stretching force constant (F) and the number of bonds per unit volume (nb). Densities, molar volume have been measured as a function of MoO3 content. Linear variation in density and in the molar volume has been observed and is credited to the role of MoO3 in the investigated glasses. Based on the properties like good stability and bond strength, investigated glasses possibly suitable for the design of optoelectronic devices.

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