Abstract
A structural analysis for dibutoxyphosphoryl benzylisothiourea (DBBT) was carried out by mass spectrometry, 1H NMR, 13C NMR, infrared and Raman spectroscopy. The Fourier transform infrared and Fourier transform Raman spectra of liquid of DBBT were carried out with the purpose of studying the tautomerism (structures I and II) and the behavior of the more polar absorption’s bands in different solvents, i.e., absorption’s of the PO and CN bands. The results suggest the existence of tautomerism in the pure (liquid) compound and in solution of CHCl 3, CH 2Cl 2, CHBr 3, and THF, C 2H 4Cl 2 and C 2H 4Br 2. The solvent interaction with the PO band was characterized by the presence of a new band in the region of the OH absorption. A vibrational assignment of the IR bands and Raman shifts was done and is proposed in this paper.
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