Strontium Doping-Tailored Inverse Spinel Phase in Cobalt Chromite with Enhanced photo-degradation of Ofloxaci

Abstract

Spinel materials are attractive to photocatalytic degradation of contaminants. In this study, strontium (Sr) doped spinel cobalt chromite (CoCr2O4) was synthesized by solution combustion method and characterized using techniques such as X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance (EPR), and electrochemical impedance spectroscopy (EIS). 30 -50 nm- cubic CoCr2O4 nanocrystals were obtained, and phase transitions of CoO6→CoO4 and CrO4→CrO6 occurred as the Sr doping content increased until 0.6% Sr doped sample displayed an inverse spinel phase. The modifications in composition and structure induced the co-existence of multivalent states for Co and Cr, which in turn changed the optical, complex impedance, and magnetic spin state of CoCr2O4. The 0.6% Sr-doped sample showed the highest photocatalytic efficiency of 93% due to enhanced optical absorption, reduced energy band gap, oxygen vacancies formation, and a high spin state of Co. The XRD structure and photocatalytic activity remained stable even after five cycles without any leakage of metal elements. The degradation pathway and Mott-Schottky curves were employed to elucidate the mechanism behind this enhancement. The strategy employed in this study proved effective, and the synthesized materials show promise for the photocatalytic degradation of contaminants.