Abstract
ABSTRACTTwo segments of horizontally grown crystalline ZnO nanorods (NRs) connected with an amorphous layer have been successfully and reproducibly synthesized using one-step hydrothermal technique by controlling the growth rate. The confocal photoluminescence (PL) imaging and spectroscopy of twin ZnO NRs at different temperatures shows intense red emission with comparably week UV emission. The strong red emission from the twin NRs is a consequence of structural imperfections. Both UV and red bands showed signatures of strong temperature dependent exciton-phonon scattering. Using the intensity ratio of the UV and red emissions, we show that the individual ZnO NRs can be used as highly sensitive cryogenic temperature sensors below ∼175 K.
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