Abstract

Several hitherto unknown acid selenites of divalent metals have been prepared and characterized by means of infrared spectroscopy and X-ray structure determination. The relations between the OH⋯O stretching and bending vibrations and the OH⋯O distances of the strongly hydrogen—bonded hydroxyl groups of these compounds and of some other acid selenites are presented. They are discussed with respect to the nature of the ABC trio-bands in the ν(OH) stretching mode region of strongly hydrogen-bonded systems.

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