Abstract

The soaring growth of flexible electronic devices has boosted the demand for electromagnetic interference (EMI) shielding materials with excellent stretchability, stability and even breathability. However, it is still a challenge to develop conductive materials with outstanding stretchable EMI shielding performance. In this work, we developed a textile with porous wrinkled conductive network through in situ polydopamine-assisted deposition of silver nanoparticles (AgNPs) on wrinkled fiber mat and polydimethylsiloxane post modification. This unique wrinkled conductive networks endows the textile with excellent electrical conductivity (103700 S/m), good breathability, superhydrophobicity, and ultra-high stretchable EMI shielding properties. The EMI shielding effectiveness (EMI SE) of the textile reaches 101.1 dB in unstretched state and still maintains at 94.1 dB at 100 % tensile strain. The superhigh EMI SE under such a high strain is much higher than the previously reported results so far. Moreover, the textile shows exceptionally good cyclic tensile durability under 100 % stain. After 1000 tensile cycles with 100 % strain, the EMI SE of sample only drops by 3.8 %. This work provides a new path for developing stretchable high EMI shielding performance materials, which is of great significance to solve the EMI problems of emerging flexible and wearable electronic devices.

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