Abstract

Wearable electronics, such as sensors, actuators, and supercapacitors, have attracted broad interest owing to their promising applications. Nevertheless, practical problems involving their sensitivity and stretchability remain as challenges. In this work, efforts were devoted to fabricating a highly stretchable and sensitive strain sensor based on dip-coating of graphene onto an electrospun thermoplastic polyurethane (TPU) nanofibrous membrane, followed by spinning of the TPU/graphene nanomembrane into an intertwined-coil configuration. Owing to the intertwined-coil configuration and the synergy of the two structures (nanoscale fiber gap and microscale twisting of the fiber gap), the conductive strain sensor showed a stretchability of 1100%. The self-inter-locking of the sensor prevents the coils from uncoiling. Thanks to the intertwined-coil configuration, most of the fibers were wrapped into the coils in the configuration, thus avoiding the falling off of graphene. This special configuration also endowed our strain sensor with an ability of recovery under a strain of 400%, which is higher than the stretching limit of knees and elbows in human motion. The strain sensor detected not only subtle movements (such as perceiving a pulse and identifying spoken words), but also large movements (such as recognizing the motion of fingers, wrists, knees, etc.), showing promising application potential to perform as flexible strain sensors.

Highlights

  • Flexible conductive wearable devices have drawn great attention for the dramatic development of artificial intelligence technology [1,2,3,4,5,6,7]

  • The sensors can recognize the movement of humans, including subtle movements and large movements

  • A highly stretchable strain sensor based on thermoplastic polyurethane (TPU) and graphene with an intertwined-coil configuration was fabricated

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Summary

Introduction

Flexible conductive wearable devices have drawn great attention for the dramatic development of artificial intelligence technology [1,2,3,4,5,6,7]. As a fundamental type of flexible conductive wearable electronics, have become a building block of electronic devices. Conducting polymers, nanowires, metal nanoparticles, carbon nanotubes, and ionic liquids have been deposited on the surface or embedded in the matrix of a strain sensor to improve its sensitivity. Because of its large surface area, high thermal conductivity, good chemical resistance (to acids, bases, and salts), good thermal stability, and unique electrical and mechanical properties, graphene has attracted considerable attention for use in strain sensors [16,23,45,46,47,48,49,50,51,52]. A highly stretchable strain sensor based on thermoplastic polyurethane (TPU) and graphene with an intertwined-coil configuration was fabricated.

Experimental Section
Characterizations
Morphology
Detection of Pressure
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