Stretchable Carbon and Silver Inks for Wearable Applications.

Andrew Claypole,Tim Claypole,David Gethin,Liam Kilduff,James Claypole

doi:10.3390/nano11051200

Andrew Claypole, Tim Claypole + Show 3 more

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https://doi.org/10.3390/nano11051200

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Abstract

For wearable electronic devices to be fully integrated into garments, without restricting or impeding movement, requires flexible and stretchable inks and coatings, which must have consistent performance and recover from mechanical strain. Combining Carbon Black (CB) and ammonia plasma functionalized Graphite Nanoplatelets (GNPs) in a Thermoplastic Polyurethane (TPU) resin created a conductive ink that could stretch to substrate failure (>300% nominal strain) and cyclic strains of up to 100% while maintaining an electrical network. This highly stretchable, conductive screen-printable ink was developed using relatively low-cost carbon materials and scalable processes making it a candidate for future wearable developments. The electromechanical performance of the carbon ink for wearable technology is compared to a screen-printable silver as a control. After initial plastic deformation and the alignment of the nano carbons in the matrix, the electrical performance was consistent under cycling to 100% nominal strain. Although the GNP flakes are pulled further apart a consistent, but less conductive path remains through the CB/TPU matrix. In contrast to the nano carbon ink, a more conductive ink made using silver flakes lost conductivity at 166% nominal strain falling short of the substrate failure strain. This was attributed to the failure of direct contact between the silver flakes.

Highlights

Introduction and Literature ReviewWearable electronics, such as fitness trackers, are increasingly being used within the sport, fitness and health industries to improve our health, wellbeing and athletic performance [1]
This study demonstrates the performance of a low cost, highly scalable, high conductivity stretchable screen-printable Graphite Nanoplatelets (GNPs)/Carbon Black (CB) ink and compares it to a silver ink in the same resin system
GNP/CB/Thermoplastic Polyurethane (TPU) ink showed improved electrical performance when compared with similar inks in the literature [13,22,29] with a bulk resistivity of 0.196 ± 0.013 Ω·cm, which is close to the performance of conventional conductive inks [18,20]

Summary

Introduction

Wearable electronics, such as fitness trackers, are increasingly being used within the sport, fitness and health industries to improve our health, wellbeing and athletic performance [1]. Many of these devices are based upon conventional electronics manufactured upon rigid silicone boards which can make garments uncomfortable and impractical for many uses [1,2,3]. For the large scale uptake of wearable e-textile technologies, devices must be lightweight, mechanically robust, durable, capable of withstanding bending and stretching, machine washable, aesthetically pleasing and must not impede the garment’s ability to conform to body curvatures [3,4,5,6]. For devices to be truly anatomically compliant requires the inks to maintain a conductive path under severe mechanical deformations [4,6]

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