Abstract

AbstractThe stress–strain relationships of crystallizable and noncrystallizable elastomers were determined in unswollen and swollen states. As expected, if a noncrystallizable elastomer is stretched and held at a fixed length, the subsequent swelling in a solvent decreases the stress as the elastomer is swollen. On the other hand, if a crystallizable elastomer is stretched to a medium extension at which some crystallization has occurred and held at that length, the subsequent swelling in a suitable solvent increases the stress as the elastomer is swollen and the crystallites are dissolved by the solvent. The phenomena are explained in terms of the network swelling and the crystallization and melting induced by the applied stress and the swelling solvent.

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