Abstract

This research is aimed at comparing the stress dependency of creep viscoelastic behavior for glass/epoxy composite and neat epoxy close to the glass transition temperature and room temperature. Long-term creep performance of quasi-unidirectional composites and quasi-isotropic stacking sequence composites is modeled based on the time-stress superposition principle (TSSP). Linearity and nonlinearity of viscoelastic behavior and stress-dependence correlations were investigated for quasi-isotropic stacking sequence composite at 25°C and 50°C (near the glass transition temperature). Stress dependency of creep stages (primary, secondary, and tertiary) of neat epoxy was evaluated at this range of temperature. The prediction results of composite at room temperature show that the raising of the stress levels leads to the acceleration of viscoelastic strain values, but the creep compliance does not present any dependency. Besides, the reduction of viscoelastic ability is realized by measuring less amount of creep compliance at higher stress level in the glass transition temperature. These observations confirmed the linearity and nonlinearity of viscoelastic behavior at room and glass transition temperature, respectively. Similar results of neat epoxy revealed that the increase in the stress level accelerates the strain values at room temperature and decreases the creep resistance at glass transition temperature. Failure morphologies of epoxy sample fractured at room temperature are included scarp, cusp, and river line; however, close to the glass transition temperature, more expansive mirror zones appeared. Fiber architecture significantly affected the secondary stage regime by providing load-bearing ability. Thereby, creep rate reduction and enhancement of creep lifetime and creep resistance would be reported using unidirectional reinforcing in contrast to those of the multilayer sequence one.

Highlights

  • Epoxy has gained enormous attention to use as a matrix in fiber-reinforced polymer (FRP) composites, due to relatively high chemical resistance, low volatility, low shrinkage on curing, and relatively high specific strength and modulus [1]

  • Viscoelastic characterization under the impact of elevated temperature and Tg throughout the creep tests has been performed on polymeric matrix composites (PMC) in previous researches

  • (2) Creep compliance is independent on applied stress levels at room temperature that confirm the linearity of viscoelastic behavior, whereas near the glass transition temperature, the nonlinearity can be observed by compliance dependency on stress levels

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Summary

Introduction

Epoxy has gained enormous attention to use as a matrix in fiber-reinforced polymer (FRP) composites, due to relatively high chemical resistance, low volatility, low shrinkage on curing, and relatively high specific strength and modulus [1]. High viscoelastic ability is often the primary requisite for reliable long-term structural applications [4]. The viscoelastic properties of polymeric materials can be evaluated using the creep tests [5]. At long-term creep loading, nonlinear viscoelastic response increased by adding modifiers to asphalt binder [6] and increasing the stress and temperature value [7]. Viscoelastic characterization under the impact of elevated temperature and Tg throughout the creep tests has been performed on polymeric matrix composites (PMC) in previous researches

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