Abstract

Degradation of an Inconel 601 superalloy subjected to a eutectic mixture of carbonate salt at 450°C was studied using advanced microscopy and microanalysis techniques. On the outside of the vessel, long term exposure to elevated temperature led to intergranular stress corrosion cracking via a stress assisted oxidation process. Elemental analysis verified diffusion controlled de-alloying of Ni and Cr from grain boundaries. Transmission electron microscopy showed that a (CrFeNiAl)3O4 oxide phase was formed at grain boundaries as a result of oxygen penetration. Intergranular cracking appeared due to the presence of residual stresses and microstructural heterogeneities facilitated the crack branching.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call