Strategies for risk assessment of existing chemicals in soil

Abstract

In the risk assessment of industrial chemicals, an assessment of the risk to soil should be performed whenever relevant inputs occur via the following pathways: application of sewage sludge, wet or dry deposition, application as a pesticide constituent (e.g. solvent or metabolite), irrigation. An evaluation of the results for 34 chemicals from the first EU priority list showed that only 35% of the risk assessments for the terrestrial compartment were performed on the basis of at least 2 valid tests with soil organisms. In the vast majority of cases, the equilibrium partitioning method was used to extrapolate from aquatic to soil toxicity. However, no indications exist for a correlation between aquatic and terrestrial toxicity. Moreover, the exposure routes for soil organisms (uptake via pore water, air included in soil pores, ingestion of soil particles) are much more complex than those for aquatic organisms. As a new approach, it is therefore suggested that, in cases of relevant exposure (e.g. estimated or measured concentrations of >10 µg/kg), an assessment should generally be performed on the basis of valid terrestrial tests rather than on an extrapolation from the aquatic toxicity. It is recommended that prolonged exposure tests should be used already for an initial assessment of substances that have a strong tendency to adsorb on soil particles and thus a long residence time in soil. A decision scheme for the risk assessment of industrial chemicals in soil is presented, trigger values, testing strategies as well as assessment factors for derivation of a Predicted No Effect Concentration (PNECsoil) are discussed. An example of a terrestrial risk assessment for substances from the first EU priority list is given in order to illustrate current practice.