Strategies for Manipulating Phonon Transport in Solids.

Abstract

In this review, we summarize the recent efforts on manipulating phonon transport in solids by using specific techniques that modify their phonon thermal conductivity (i.e., specific heat, phonon group velocity, and mean free path) and phonon thermal conductance (i.e., transmission probability and density of states). The strategies discussed for tuning thermal conductivity are as follows: large unit cell approach and liquid-like conduction for maneuvering specific heat; rattler, mini-bandgap, and phonon confinement for manipulating phonon group velocity; nanoparticles, nanosized grains, coated grains, alloy (isotope) scattering, selection rules in phonon dispersion, Grüneisen parameter, lone-pair electronics, dynamic disorder, and local static distortion for restricting mean free path. We have also included the discussion on tuning phonon thermal conductance, as thermal conduction can be viewed as a transmission process. Additionally, phonon filtering, ballistic transport, and waveguiding are discussed to alter density of states and transmission probability. We hope this review can bring meaningful insights to the researchers in the field of phonon transport in solids.