Strategically Designed Pd-Induced Changes in Alkaline Hydrogen Evolution Reaction and Oxygen Evolution Reaction Performances of Electrochemical Water Oxidation by the Galvanically Synthesized MoO2/MoO3 Composite Thin Film.

Abstract

Electrochemical water oxidation is believed to be an effective pathway to produce clean, carbon-free, and environmentally sustainable green energy. In this work, we report a simple, easy-to-construct, facile, low-cost, and single-step galvanic technique to synthesize a Pd-supported temperature-assisted MoOx thin film nanocomposite for effective water oxidation. The most suitable nanocomposite exhibits very low overpotential at 10 mA/cm2 with smaller Tafel slope values for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) processes in an alkaline medium. The formation of a metal oxide-metal junction accelerates the growth of more active sites, promoting induced electronic synergism at the MoOx-Pd interface. This endows higher electrical conductivity and faster electron transfer kinetics, thus accelerating the faster water dissociation reaction following the Tafel-Volmer mechanism to boost the HER process in an alkaline medium. The excellent electrochemical HER and OER performances of our electrocatalyst even supersede the accomplishments of the benchmark catalysts Pt/C and RuO2. Moreover, neither of these two catalysts demonstrates both catalytic reactions, i.e., HER and OER at the same time, which have been observed for our synthesized catalyst. Our findings illustrate the potential of a thin-film MoOx-Pd nanocomposite to be an exceedingly effective electrocatalyst developed by interface engineering strategies. This also provides insight into designing several other semiconductor composite catalysts using simple synthesis techniques for highly efficient HER/OER processes that could be alternatives to benchmark electrocatalysts for water electrolysis.