Strain engineering of PtMn alloy enclosed by high-indexed facets boost ethanol electrooxidation

Abstract

Surface strain engineering has proven to be an efficient strategy to enhance catalytic properties of platinum (Pt)-based catalysts for electrooxidation reactions. Herein, the S-doped PtMn concave cubes (CNCs) enclosed with high index facets (HIFs) and regulatable surface strain are successfully fabricated by two steps hydrothermal method. The S element with electrophilic property can modify the near-surface of PtMn nanocrystals, altering the electronic structure of Pt to effectively regulate the adsorption/desorption of intermediates in the ethanol electrooxidation reaction (EOR). The PtMnS1.1 catalyst with optimal surface strain delivered extraordinary catalytic performance on EOR in acidic media, with a specific activity of 2.88 mA/cm2 and mass activity of 1.10 mA/μgPt, which is 4.1 and 2.2 times larger than that of state-of-the-art Pt/C catalyst, respectively. Additionally, the PtMnS1.1 catalyst also achieve excellent catalytic properties in alkaline electrolyte for EOR. The results of kinetic studies indicated that the surface strain and modified electronic structure can degrade the activation energy barrier during the process of EOR, which is beneficial for enhance the reaction rate. This work provides a promising approach to construct highly efficient electrocatalysts with tunable surface strain effects for clean energy electro-chemical reactions.