Strain controlled ferroelectric switching time of BiFeO3 capacitors

Abstract

The ferroelectric switching kinetics of BiFeO3 capacitors grown on a piezoelectric substrate has been investigated in different strain states and at various temperatures. The switching behavior is in good agreement with the Kolmogorov-Avrami-Ishibashi model. The effect of reversible biaxial in-plane compression on the switching time is an enhancement at low electric field and a reduction at high field. The two field regimes are found to correspond to the creep and the depinning of domain walls. The strain effect on the switching time depends strongly on temperature and reaches a tenfold slowing down upon ∼0.1% of biaxial compression at 50 K. This work provides a route to realize strain control of ferroelectric switching kinetics in BiFeO3 and is significant for potential applications.