Abstract
A straightforward route to a well-soluble dibenzo[ g , p ]chrysene (DBC) scaffold is described. The scaffold is 2,7-dibromo-10,15-dibutyl DBC, in which two butyl groups work as a solubilizing agent and two bromines play a role of changeable tags. This solution-processable DBC enabled diversity-oriented approaches for synthesis of solubilizing DBC derivatives: actually, one of the two bromines selectively undertook the first transformation, and the other bromine was subjected to the second substitution reaction. Thus, the new DBC platform provides a general entry for creation of new polycyclic aromatic hydrocarbons.
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