Straightforward Preparation of a Solid‐state Luminescent Cu11 Polymetallic Assembly via Adaptive Coordination‐driven Supramolecular Chemistry

Abstract

The tridentate dpmp ligand was reacted with CuI salt and cyano ligand affording selectively and unexpectedly the polymetallic Cu11 complex 2 along one‐step reaction. The formation of this derivative 2 can be explained by self‐assembling processes controlled by adaptive coordination‐driven supramolecular chemistry. The solid‐state photophysical behavior of 2 was studied suggesting TADF properties.