Abstract
Reaction of pentacyclo[5.4.0.02,6.0 3 , 1 0 .0 5 . 8 ]undecane-8-thione (7) with diazomethane (9a) and 2-diazopropane (9b) afforded the 1,3,4-thiadiazolines 12a and 12c, which subsequently were used as precursors of reactive thiocarbonyl ylides 13a,b, respectively. Diphenyldiazomethane reacted rapidly with 7 to yield thiirane 14c as the final product. When decomposition of 12a or 12c was carried out in the presence of dipolarophiles, such as TCNE, DMAD or N-methylmaleinimide, new cage-functionalized heterocvcles were obtained.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
