Stornesite-(Y), (Y, Ca) 2Na6(Ca,Na)8(Mg,Fe)43(PO4)36, the first terrestrial Mg-dominant member of the fillowite group, from granulite-facies paragneiss in the Larsemann Hills, Prydz Bay, East Antarctica

Abstract

Stornesite-(Y), end-member formula Y□ 2 Na 6 (Ca 5 Na 3 )Mg 43 (PO 4 ) 36 , is a new Y-dominant analog of the meteoritic mineral chladniite. A representative electron microprobe analysis is SiO 2 = 0.02, P 2 O 5 = 48.11, SO 3 = 0.05, MgO = 23.16, MnO = 0.24, FeO = 15.55, Na 2 O = 5.04, CaO = 5.66, SrO = 0.02, Y 2 O 3 = 1.43, Yb 2 O 3 = 0.24, UO 2 = 0.01, Sum = 99.53 wt%, which gives Y 0.68 Yb 0.06 Na 8.69 Ca 5.40 Sr 0.01 Mg 30.71 Fe 11.56 Mn 0.18 Si 0.02 S 0.04 P 36.22 O 144 . Overall, Y + REE range from 0.542 to 0.985 atoms per formula, and atomic Mg/(Mg + Fe) ratio from 0.684 to 0.749. Single-crystal X-ray diffraction gives trigonal symmetry, R 3, a = 14.9628(27) A, c = 42.756(11) A, V = 8290(4) A 3 , calculated density = 3.196 g/cm 3 , Z = 3. The mineral is isostructural with synthetic chladniite, but the (0, 0, 0) site is dominantly occupied by Y instead of Ca. Bond lengths are considerably shorter than for Ca sites; Y and Yb are fully ordered at this site, which is our rationale for recognizing stornesite-(Y) as a distinct species. The strongest lines in the powder pattern [ d in A, ( I ), ( hkl )] are 3.67 (40) (0 3 6, 3 0 6), 3.52 (40) (0 0 12, 3 1 2, 1 3 2), 2.94 (60) (0 1 14, 3 2 2, 2 3 2), 2.73 (100) (2 0 14, 0 3 12, 3 0 12), 1.84 (40) (1 5 14, 5 1 14, 0 6 12, 6 0 12). The mineral is optically uniaxial +, n ω = 1.6215(10) and n e = 1.6250(10) at 589 nm. Its color is pale yellow in standard thin sections. Stornesite-(Y) is found as inclusions in fluorapatite nodules in two paragneiss specimens from Johnston Fjord, Stornes Peninsula (whence the name) and in a third from Brattnevet, Larsemann Hills. Associated minerals are wagnerite, xenotime-(Y), monazite-(Ce), P-bearing K-feldspar, biotite, sillimanite, quartz, and pyrite; it is commonly altered to rusty material and secondary phosphates. Grains are anhedral, subhedral, or locally euhedral with hexagonal or rhombic outlines; maximum dimensions are 1 × 0.25 mm. It is inferred to have formed at 800–860 °C, 6–7 kbar by reaction of biotite with an anatectic melt locally enriched in P by interaction with fluorapatite.