Abstract

A new method, viz. stopped flow polymerization, has been employed to observe the quasi-living polymerization state of propene. It was found that the molecular weight distribution was maintained constant from the very start of the polymerization process ( i.e. after 0.1 s) and that the concentration of Al(C 2H 5) 3 used as well as method of catalyst preparation influenced some of the kinetic parameters.

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