Abstract
We report here the first example of a stoichiometric hydroformylation using HMn(CO) 5. Treatment of a hexane solution of 1,2-diphenyl-3,3-dimethylcyclopropene with HMn(CO) 5 at 55°C gave after 5 h a 27% yield of aldehydes, 87% cis and 13% trans. The other major products were cis-(87%)-, and trans-(13%)-1,2-diphenyl-3,3-dimethylcyclopropane. Evidence for a radical intermediate is presented.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
