Abstract

We provide a stochastic thermodynamic description across scales for N identical units with all-to-all interactions that are driven away from equilibrium by different reservoirs and external forces. We start at the microscopic level with Poisson rates describing transitions between many-body states. We then identify an exact coarse graining leading to a mesoscopic description in terms of Poisson transitions between system occupations. We proceed studying macroscopic fluctuations using the Martin–Siggia–Rose formalism and large deviation theory. In the macroscopic limit (N → ∞), we derive the exact nonlinear (mean-field) rate equation describing the deterministic dynamics of the most likely occupations. We identify the scaling of the energetics and kinetics ensuring thermodynamic consistency (including the detailed fluctuation theorem) across microscopic, mesoscopic and macroscopic scales. The conceptually different nature of the ‘Shannon entropy’ (and of the ensuing stochastic thermodynamics) at different scales is also outlined. Macroscopic fluctuations are calculated semi-analytically in an out-of-equilibrium Ising model. Our work provides a powerful framework to study thermodynamics of nonequilibrium phase transitions.

Highlights

  • Interacting many body systems can give rise to a very rich variety of emergent behaviours such as phase transitions

  • We demonstrate that stochastic thermodynamics is invariant under this exact coarse-graining of the stochastic dynamics, provided one considers initial conditions which are uniform within each mesostate, or for systems in stationary states

  • Using a path integral representation of the stochastic dynamics (Martin–Siggia–Rose formalism), we identify the scaling in system size of the rates and of the energy that is necessary to ensure that the macroscopic fluctuations satisfy a detailed fluctuation theorem and are thermodynamically consistent

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Summary

12 June 2020

Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Keywords: nonequilibrium thermodynamics, nonequilibrium statistical mechanics, many-body systems, nonequilibrium phase transitions

Introduction
Microscopic description
Trajectory definitions
Detailed fluctuation theorems across scales
Macroscopic theory
Example
Conclusion
Full Text
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