Stochastic order parameter dynamics for phase coexistence in heat conduction.

Abstract

We propose a stochastic order parameter model for describing phase coexistence in steady heat conduction near equilibrium. By analyzing the stochastic dynamics with a nonequilibrium adiabatic boundary condition, where total energy is conserved over time, we derive a variational principle that determines thermodynamic properties in nonequilibrium steady states. The resulting variational principle indicates that the temperature of the interface between the ordered region and the disordered region becomes greater (less) than the equilibrium transition temperature in the linear response regime when the thermal conductivity in the ordered region is less (greater) than that in the disordered region. This means that a superheated ordered (supercooled disordered) state appears near the interface, which was predicted by an extended framework of thermodynamics proposed in Nakagawa and Sasa [Liquid-Gas Transitions in Steady Heat Conduction, Phys.Rev. Lett. 119, 260602 (2017)PRLTAO0031-900710.1103/PhysRevLett.119.260602.].