Abstract
Stochastic considerations on relatively strong hydrogen bonds lead to a conclusion that the temperature has a considerable effect on the low frequency absorption band which, is ascribed to the “tunneling” transition between split levels of ground vibrational state. That influence should be the strongest one for hydrogen bonds of intermediate strength. The investigations carried out on a number of relatively strong symmetrical, in a dynamical sense, N-H···N and O-H···O hydrogen bonds have shown the actual existence of that effect, which is in a qualitative agreement with the one predicted from theory.
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