Abstract

The structure of the Ni(110)-(2 × 1)-2CO system has been studied with scanning tunneling microscopy (STM) at room temperature. Contrary to many previous studies, it is found that atomically-resolved STM imaging of CO molecules is attainable. By comparing the apparent CO adlayer registry with coadsorbed low concentrations of O and S, it is found that the CO molecules bond in short-bridge sites along the Ni [11̄0] rows and alternately tilt away from the normal direction within the (001) plane.

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