Abstract

The M-band emission in ZnO at 1.7 K is investigated by tuning the excitation light through the A-B exciton region. Externally stimulated two-photon emission from excitonic molecules is observed when the pump photon energy is resonant with the upper B-polariton. The experiments suggest two excitonic molecule levels separated by 4.6 meV and with a ground state energy E M = 6.7394 eV.

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