Abstract

We consider the conditions necessary for the development of an inverted population among the energy levels of free atoms in a medium exposed to radiation in spectral non-equilibrium. In particular, we focus on monochromatic radiation occurring as a result of an accidental wavelength coincidence between a pumping emission line and a pumped absorption line in two different elements. We examine especially the influence of `pseudo-metastable' states (at medium excitation) in the complex spectrum of Fe II, which cause a `bottleneck' in the radiative decay leading to an inverted level population. We also discuss the effect of `spectral compression' of the Lyman continuum into HLyα radiation at a high effective temperature. In conclusion we describe those differences between microwave astrophysical masers (APM) and optical astrophysical lasers (APL) that make the latter a more rare phenomenon in Nature.

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