Abstract
AbstractIn this study, we estimated the chain nature of atactic and stereoregular poly(substituted methylene)s containing a phenylmethoxy side chain at each main‐chain backbone carbon atom using synchrotron X‐ray scattering to understand the topological and conformational properties of these rigid polymers. The atactic poly(substituted methylene) showed a linear chain nature. Contrastingly, the stereoregular poly(substituted methylene) exhibited a random coil structure. © 2018 Society of Chemical Industry
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