Abstract

The magnetic response of the Fe@Sn12 cluster is investigated by magnetic beam deflection experiments. In contrast to Mn@Sn12, the molecular beam of this cluster is deflected almost exclusively toward increasing field, also at low temperatures, supposable due to Jahn–Teller induced distortions of the tin cage. The magnitude of the magnetic dipole moment is extracted from the shift of the beam profile and provides evidence for a (partially quenched) contribution of electronic orbital angular momentum to the magnetic dipole moment.

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