Abstract
Abstract Reactions of tert-butyl (chloro) dimethylsilane with primary and secondary amines or their lithium salts produce compounds having the general formula t-BuMe2SiNRR1. These compounds are distillable liquids that show high stabilities toward hydrolysis. Their chemical reactivities are generally lower than their trimethylsilyl analogs. tert-Butyldimethylsilyl (trimethylsilyl)-benzylamine, C6H5CH2N(SiMe2 t-Bu)SiMe3, is readily made by lithiation and subsequent silylation of C6H5CH2NHSiMe2 t-Bu but cannot be prepared with similar ease from trimethylsilylbenzylamine.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
