Abstract
An approach to the problem of diffusion-controlled chemical reactions has been proposed based on a direct kinematic interpretation of relative diffusion accompanied with reactions. This approximation can be mathematically founded on the uncoupling procedure in the equation conventionally used for calculations of quasi-stationary reaction rate constants. This procedure appears to employ the closure approximation by Wilemsky and Fixman in the general theory of diffusion-controlled bimolecular reactions. On the basis of this approach an approximate analytic solution of the problem of stereospecific chemical reactions has been obtained which differs from the accurate one only by several percent.
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