Abstract
The activation parameters for the water substitution reactions of some organocobaloximes with thiourea in aqueous solution at I = 1 M (NaNO 3) are reported and discussed. Scatter in an isokinetic plot indicates that more than one interaction mechanism is at play. The ΔH* values are shown to be influenced by the electron withdrawing power and by the steric bulk of alkyl group. The influence of these factors on ΔS* cannot be rationalized.
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