Abstract
Substituted trimethylsilyldienes 12a-14a were prepared in high yield and total stereocontrol using a metallate rearrangement induced by the reaction of the dilithiumbis-[(E)-2-(trimethylsilyl)ethenyl]cyanocuprate 11 with the 5-lithio-2,3-dihydrofuran 7-9. Trimethylsilyldienes 12-14 were then submitted to an electrophilic substitution in the presence of acetyl chloride and aluminium trichloride for an access to the corresponding dienones 15-22. Results were tentatively explained with the aid of a modeling study.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
