Abstract

1. New catalytic systems simulating the structure of the active centers in the polymerization of dienes were studied, and it was shown that the stereospecificity of their action is related primarily to the electronic state of the transition metal. 2. The mechanism of Stereoregulation was considered on the basis of the experimental data. The possibility of the formation ofπ-allylactive centers in various systems containing compounds of the transition metal was demonstrated.

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