Abstract
Wahlweise: Die Drei-Enzyme-Kassette MarG/H/I steuert die stereospezifische Biosynthese von β-Methyltryptophan aus L-Tryptophan (1). MarG/I wandelt 1 in (2S,3R)-β-Methyltryptophan um, während MarG/I in Kombination mit MarH aus 1 das (2S,3S)-β-Methyltryptophan erzeugt. MarH dient als stereochemischer Schalter, indem es die Inversion des β-Stereozentrums katalysiert.
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