Abstract
Stereoselectivity of mixed complexes of copper(II) with R- and S-isomers of aminocarboxylic acids (valine, ornithine, asparagine, and arginine), and aminophosphonic acids in an optically active form was studied by the method of potentiometric titration at 25°C and μ 0.1 in an aqueous medium. It was shown that the formation of mixed complexes of amino acids and APA with the same optical configuration generally occurs in preference to the formation of complexes with ligands having an opposite configuration.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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