Abstract
The reaction of allylstannanes with α,β-unsaturated acyliron complexes and AlCl 3 to give five-membered rings was found to be highly stereoselective. Reaction of the trans-crotonyliron complex with allyltributyltin provided exclusively the adduct where the acyliron and methyl groups are trans. Reaction of the cis isomer provided the corresponding cis cyclopentane.
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