Abstract
Palladium-catalysed hydrostannylation of acetylenic sulfones (R–C≡C–SO2Ar) in benzene at room temperature gives stereoselectively (E)-α-stannylvinyl sulfones in good to high yields. (E)-α-Stannylvinyl sulfones are difunctional group reagents which undergo Stille coupling reaction with aryl halides in the presence of Pd(PPh3)4 and CuI co-catalyst to afford stereoselectively (Z)-1,2-disubstituted vinyl sulfones in good yields.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
