Abstract

Abstract Stereoselective synthesis of trisubstituted olefins: ethyl 4‐methyl‐( E )‐4,8‐nonadienoate reactant: 49.4 g. (0.546 mole) of 4‐chloro‐1‐butene reactant: 40.1 g. (0.572 mole) of methacrolein intermediate: 2‐methyl‐1,6‐heptadien‐3‐ol reactant: 186 g. (1.15 moles) of ethyl orthoacetate reactant: 0.70 g. (0.0094 mole) of propionic acid product: ethyl 4‐methyl‐( E )‐4,8‐nonadienoate reactant: 3‐buten‐1‐ol

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