Abstract
AbstractA number of P‐stereogenic N‐phosphinyl compounds were stereoselectively prepared in good yields by a straightforward approach, thanks to the diversified and, up until now, unexplored reactivity of (R)‐ and (S)‐dicyclohexylidene‐D‐glucose methyl phenyl phosphinates toward metal amides. Under adequate conditions, structurally different phosphinamides with one or two P‐chiral centers were obtained.
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