Abstract
Chiral γ-N,N-dibenzylamino-substituted α,β-unsaturated carboxylic acid esters and dicarboxylic acid esters, prepared in enantiomerically pure form from L-amino acids, undergo diastereoselective Michael addition reactions with nitrogen nucleophiles of the type Me 3SiNHOSiMe 3 and CH 3NHOH; the products are novel β-amino hydroxylamine derivatives having two defined stereogenic centers.
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