Abstract
A general and mostly highly stereoselective method for effective synthesis of 1-boryl-3-(silyl)propenes via one-step catalytic processes, i.e. silylative coupling of vinylsilanes with allyl boronates, borylative coupling of vinyl boronates with allylsilanes catalysed by [RuHCl(CO)(PCy3)2] and cross-metathesis of respective derivatives in the presence of Grubbs catalysts, is described.
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