Abstract
Ring-opening polymerization of D,L-lactide was stereoselectively achieved using newly designed aluminum alkoxide complexes as initiators. These half-SALEN aluminum complexes bearing tridentate nonchiral Schiff-base ligands are racemates, which provide chirality in the aluminum centers, efficiently afforded a stereoblock copolymer of D,L-LA. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
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