Abstract
In this paper the authors describe a highly enantio- and diastereoselective protocol for restructuring of 3-arylcyclobutanols into 1-indanols. Reactions were carried out with high yields (79-98%) as well as with high diastereoselectivities (dr = 85:15 to 93:7) and excellent enantioselectivities (97-99% ee). This method is particularly noteworthy, since the obtained products contain two chiral quaternary centers.
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